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Rotation and Macroturbulence in Metal-Poor Field Red Giant and Red Horizontal Branch Stars
We report the results for rotational velocities, Vrot sin i,and macroturbulence dispersions, ζRT, for 12 metal-poorfield red giant branch (RGB) stars and 7 metal-poor field red horizontalbranch (RHB) stars. The results are based on Fourier transform analysesof absorption line profiles from high-resolution (R ≈ 120,000),high-S/N (≈215 per pixel; ≈345 per resolution element) spectraobtained with the Gecko spectrograph at the Canada-France-HawaiiTelescope (CFHT). The stars were selected from the authors' previousstudies of 20 RHB and 116 RGB stars, based primarily onlarger-than-average line-broadening values. We find thatζRT values for the metal-poor RGB stars are very similarto those for metal-rich disk giants studied earlier by Gray and hiscollaborators. Six of the RGB stars have small rotational values, lessthan 2.0 km s-1, while five show significantrotation/enhanced line broadening, over 3 km s-1. We confirmthe rapid rotation rate for RHB star HD 195636, found earlier byPreston. This star's rotation is comparable to that of the fastest knownrotating blue horizontal branch (BHB) stars, when allowance is made fordifferences in radii and moments of inertia. The other six RHB starshave somewhat lower rotation but show a trend to higher values at highertemperatures (lower radii). Comparing our results with those for BHBstars from Kinman et al., we find that the fraction of rapidly rotatingRHB stars is somewhat lower than is found among BHB stars. The number ofrapidly rotating RHB stars is also smaller than we would have expectedfrom the observed rotation of the RGB stars. We devise two empiricalmethods to translate our earlier line-broadening results intoVrot sin i for all the RGB and RHB stars they studied.Binning the RGB stars by luminosity, we find that most metal-poor fieldRGB stars show no detectable sign, on average, of rotation, which is notsurprising given the stars' large radii. However, the most luminousstars, with MV <= -1.5, do show net rotation, with meanvalues of 2-4 km s-1, depending on the algorithm employed,and also show signs of radial velocity jitter and mass loss. This"rotation" may in fact prove to be due to other line-broadening effects,such as shock waves or pulsation.Based on observations obtained at the Canada-France-Hawaii Telescope(CFHT) which is operated by the National Research Council of Canada, theInstitut National des Sciences de l'Univers of the Centre National de laRecherche Scientifique de France, and the University of Hawaii.

Halo Star Streams in the Solar Neighborhood
We have assembled a sample of halo stars in the solar neighborhood tolook for halo substructure in velocity and angular momentum space. Oursample (231 stars) includes red giants, RR Lyrae variable stars, and redhorizontal branch stars within 2.5 kpc of the Sun with [Fe/H] less than-1.0. It was chosen to include stars with accurate distances, spacevelocities, and metallicities, as well as well-quantified errors. Withour data set, we confirm the existence of the streams found by Helmi andcoworkers, which we refer to as the H99 streams. These streams have adouble-peaked velocity distribution in the z-direction (out of theGalactic plane). We use the results of modeling of the H99 streams byHelmi and collaborators to test how one might use vz velocityinformation and radial velocity information to detect kinematicsubstructure in the halo. We find that detecting the H99 streams withradial velocities alone would require a large sample (e.g.,approximately 150 stars within 2 kpc of the Sun and within 20° ofthe Galactic poles). In addition, we use the velocity distribution ofthe H99 streams to estimate their age. From our model of the progenitorof the H99 streams, we determine that it was accreted between 6 and 9Gyr ago. The H99 streams have [α/Fe] abundances similar to otherhalo stars in the solar neighborhood, suggesting that the gas thatformed these stars were enriched mostly by Type II supernovae. We havealso discovered in angular momentum space two other possiblesubstructures, which we refer to as the retrograde and progradeoutliers. The retrograde outliers are likely to be halo substructure,but the prograde outliers are most likely part of the smooth halo. Theretrograde outliers have significant structure in the vφdirection and show a range of [α/Fe], with two having low[α/Fe] for their [Fe/H]. The fraction of substructure stars in oursample is between 5% and 7%. The methods presented in this paper can beused to exploit the kinematic information present in future largedatabases like RAVE, SDSS-II/SEGUE, and Gaia.

Hubble Space Telescope Observations of Chromospheres in Metal-Deficient Field Giants
Hubble Space Telescope high-resolution spectra of metal-deficient fieldgiants more than double the stars in previous studies, span ~3 mag onthe red giant branch, and sample an abundance range [Fe/H] = -1 to -3.These stars, in spite of their age and low metallicity, possesschromospheric fluxes of Mg II (λ2800) that are within a factor of4 of Population I stars, and they give signs of a dependence on themetal abundance at the lowest metallicities. The Mg II k line widthsdepend on luminosity and correlate with metallicity. Line profileasymmetries reveal outflows that occur at lower luminosities(MV = -0.8) than detected in Ca K and Hα lines inmetal-poor giants, suggesting mass outflow occurs over a larger span ofthe red giant branch than previously thought and confirming that the MgII lines are good wind diagnostics. These results do not support amagnetically dominated chromosphere, but they appear more consistentwith some sort of hydrodynamic or acoustic heating of the outeratmospheres.

Oxygen abundances in metal-poor subgiants as determined from [O I], O I and OH lines
The debate on the oxygen abundances of metal-poor stars has its originin contradictory results obtained using different abundance indicators.To achieve a better understanding of the problem we have acquired highquality spectra with the Ultraviolet and Visual Echelle Spectrograph atVLT, with a signal-to-noise of the order of 100 in the near ultravioletand 500 in the optical and near infrared wavelength range. Threedifferent oxygen abundance indicators, OH ultraviolet lines around 310.0nm, the [O i] line at 630.03 nm and the O i lines at 777.1-5 nm wereobserved in the spectra of 13 metal-poor subgiants with-3.0≤[Fe/H]≤-1.5. Oxygen abundances were obtained from theanalysis of these indicators which was carried out assuming localthermodynamic equilibrium and plane-parallel model atmospheres.Abundances derived from O i were corrected for departures from localthermodynamic equilibrium. Stellar parameters were computed usingT_eff-vs.-color calibrations based on the infrared flux method andBalmer line profiles, Hipparcos parallaxes and Fe II lines. [O/Fe]values derived from the forbidden line at 630.03 nm are consistent withan oxygen/iron ratio that varies linearly with [Fe/H] as[O/Fe]=-0.09(±0.08)[Fe/H]+0.36(±0.15). Values based on theO i triplet are on average 0.19±0.22 dex(s.d.) higher than thevalues based on the forbidden line while the agreement between OHultraviolet lines and the forbidden line is much better with a meandifference of the order of -0.09±0.25 dex(s.d.). In general, ourresults follow the same trend as previously published results with theexception of the ones based on OH ultraviolet lines. In that case ourresults lie below the values which gave rise to the oxygen abundancedebate for metal-poor stars.

Li and Be depletion in metal-poor subgiants
A sample of metal-poor subgiants has been observed with the UVESspectrograph at the Very Large Telescope and abundances of Li and Behave been determined. Typical signal-to-noise per spectral bin valuesfor the co-added spectra are of the order of 500 for the ion{Li}{i} line(670.78 nm) and 100 for the ion{Be}{ii} doublet lines (313.04 nm). Thespectral analysis of the observations was carried out using the Uppsalasuite of codes and marcs (1D-LTE) model atmospheres with stellarparameters from photometry, parallaxes, isochrones and Fe ii lines.Abundance estimates of the light elements were corrected for departuresfrom local thermodynamic equilibrium in the line formation. Effectivetemperatures and Li abundances seem to be correlated and Be abundancescorrelate with [O/H]. Standard models predict Li and Be abundancesapproximately one order of magnitude lower than main-sequence valueswhich is in general agreement with the observations. On average, ourobserved depletions seem to be 0.1 dex smaller and between 0.2 and 0.4dex larger (depending on which reference is taken) than those predictedfor Li and Be, respectively. This is not surprising since the initial Liabundance, as derived from main-sequence stars on the Spite plateau, maybe systematically in error by 0.1 dex or more, and uncertainties in thespectrum normalisation and continuum drawing may affect our Beabundances systematically.

Galactic model parameters for field giants separated from field dwarfs by their 2MASS and V apparent magnitudes
We present a method which separates field dwarfs and field giants bytheir 2MASS and V apparent magnitudes. This method is based onspectroscopically selected standards and is hence reliable. We appliedit to stars in two fields, SA 54 and SA 82, and we estimated a full setof Galactic model parameters for giants including their total localspace density. Our results are in agreement with the ones given in therecent literature.

Pulkovo compilation of radial velocities for 35495 stars in a common system.
Not Available

Estimation of Carbon Abundances in Metal-Poor Stars. I. Application to the Strong G-Band Stars of Beers, Preston, and Shectman
We develop and test a method for the estimation of metallicities([Fe/H]) and carbon abundance ratios ([C/Fe]) for carbon-enhancedmetal-poor (CEMP) stars based on the application of artificial neuralnetworks, regressions, and synthesis models to medium-resolution (1-2Å) spectra and J-K colors. We calibrate this method by comparisonwith metallicities and carbon abundance determinations for 118 starswith available high-resolution analyses reported in the recentliterature. The neural network and regression approaches make use of apreviously defined set of line-strength indices quantifying the strengthof the Ca II K line and the CH G band, in conjunction with J-K colorsfrom the Two Micron All Sky Survey Point Source Catalog. The use ofnear-IR colors, as opposed to broadband B-V colors, is required becauseof the potentially large affect of strong molecular carbon bands onbluer color indices. We also explore the practicality of obtainingestimates of carbon abundances for metal-poor stars from the spectralinformation alone, i.e., without the additional information provided byphotometry, as many future samples of CEMP stars may lack such data. Wefind that although photometric information is required for theestimation of [Fe/H], it provides little improvement in our derivedestimates of [C/Fe], and hence, estimates of carbon-to-iron ratios basedsolely on line indices appear sufficiently accurate for most purposes.Although we find that the spectral synthesis approach yields the mostaccurate estimates of [C/Fe], in particular for the stars with thestrongest molecular bands, it is only marginally better than is obtainedfrom the line index approaches. Using these methods we are able toreproduce the previously measured [Fe/H] and [C/Fe] determinations withan accuracy of ~0.25 dex for stars in the metallicity interval-5.5<=[Fe/H]<=-1.0 and with 0.2<=(J-K)0<=0.8. Athigher metallicity, the Ca II K line begins to saturate, especially forthe cool stars in our program, and hence, this approach is not useful insome cases. As a first application, we estimate the abundances of [Fe/H]and [C/Fe] for the 56 stars identified as possibly carbon-rich, relativeto stars of similar metal abundance, in the sample of ``strong G-band''stars discussed by Beers, Preston, and Shectman.

The lithium content of the Galactic Halo stars
Thanks to the accurate determination of the baryon density of theuniverse by the recent cosmic microwave background experiments, updatedpredictions of the standard model of Big Bang nucleosynthesis now yieldthe initial abundance of the primordial light elements withunprecedented precision. In the case of ^7Li, the CMB+SBBN value issignificantly higher than the generally reported abundances for Pop IIstars along the so-called Spite plateau. In view of the crucialimportance of this disagreement, which has cosmological, galactic andstellar implications, we decided to tackle the most critical issues ofthe problem by revisiting a large sample of literature Li data in halostars that we assembled following some strict selection criteria on thequality of the original analyses. In the first part of the paper wefocus on the systematic uncertainties affecting the determination of theLi abundances, one of our main goal being to look for the "highestobservational accuracy achievable" for one of the largest sets of Liabundances ever assembled. We explore in great detail the temperaturescale issue with a special emphasis on reddening. We derive four sets ofeffective temperatures by applying the same colour {T}_eff calibrationbut making four different assumptions about reddening and determine theLTE lithium values for each of them. We compute the NLTE corrections andapply them to the LTE lithium abundances. We then focus on our "best"(i.e. most consistent) set of temperatures in order to discuss theinferred mean Li value and dispersion in several {T}_eff and metallicityintervals. The resulting mean Li values along the plateau for [Fe/H]≤ 1.5 are A(Li)_NLTE = 2.214±0.093 and 2.224±0.075when the lowest effective temperature considered is taken equal to 5700K and 6000 K respectively. This is a factor of 2.48 to 2.81 (dependingon the adopted SBBN model and on the effective temperature range chosento delimit the plateau) lower than the CMB+SBBN determination. We findno evidence of intrinsic dispersion. Assuming the correctness of theCMB+SBBN prediction, we are then left with the conclusion that the Liabundance along the plateau is not the pristine one, but that halo starshave undergone surface depletion during their evolution. In the secondpart of the paper we further dissect our sample in search of newconstraints on Li depletion in halo stars. By means of the Hipparcosparallaxes, we derive the evolutionary status of each of our samplestars, and re-discuss our derived Li abundances. A very surprisingresult emerges for the first time from this examination. Namely, themean Li value as well as the dispersion appear to be lower (althoughfully compatible within the errors) for the dwarfs than for the turnoffand subgiant stars. For our most homogeneous dwarfs-only sample with[Fe/H] ≤ 1.5, the mean Li abundances are A(L)_NLTE = 2.177±0.071 and 2.215±0.074 when the lowest effective temperatureconsidered is taken equal to 5700 K and 6000 K respectively. This is afactor of 2.52 to 3.06 (depending on the selected range in {T}_eff forthe plateau and on the SBBN predictions we compare to) lower than theCMB+SBBN primordial value. Instead, for the post-main sequence stars thecorresponding values are 2.260±0.1 and 2.235±0.077, whichcorrespond to a depletion factor of 2.28 to 2.52. These results,together with the finding that all the stars with Li abnormalities(strong deficiency or high content) lie on or originate from the hotside of the plateau, lead us to suggest that the most massive of thehalo stars have had a slightly different Li history than their lessmassive contemporaries. In turn, this puts strong new constraints on thepossible depletion mechanisms and reinforces Li as a stellartomographer.

Hubble Space Telescope Observations of Heavy Elements in Metal-Poor Galactic Halo Stars
We present new abundance determinations of neutron-capture elements Ge,Zr, Os, Ir, and Pt in a sample of 11 metal-poor(-3.1<=[Fe/H]<=-1.6) Galactic halo giant stars, based on HubbleSpace Telescope UV and Keck I optical high-resolution spectroscopy. Thestellar sample is dominated by r-process-rich stars such as thewell-studied CS 22892-052 and BD +17°3248 but also includes ther-process-poor, bright giant HD 122563. Our results demonstrate thatabundances of the third r-process peak elements Os, Ir, and Pt in thesemetal-poor halo stars are very well correlated among themselves and withthe abundances of the canonical r-process element Eu (determined inother studies), thus arguing for a common origin or site for r-processnucleosynthesis of heavier (Z>56) elements. However, the large (andcorrelated) scatters of [Eu, Os, Ir, Pt/Fe] suggest that the heaviestneutron-capture r-process elements are not formed in all supernovae. Incontrast, the Ge abundances of all program stars track their Feabundances, very well. An explosive process on iron peak nuclei (e.g.,the α-rich freezeout in supernovae), rather than neutron capture,appears to have been the dominant synthesis mechanism for this elementat low metallicities: Ge abundances seem completely uncorrelated withEu. The correlation (with very small scatter) of Ge and Fe abundancessuggests that Ge must have been produced rather commonly in stars, evenat early times in the Galaxy, over a wide range of metallicity. The Zrabundances show much the same behavior as Ge with (perhaps) somewhatmore scatter, suggesting some variations in abundance with respect toFe. The Zr abundances also do not vary cleanly with Eu abundances,indicating a synthesis origin different than that of heavierneutron-capture elements. Detailed abundance distributions for CS22892-052 and BD +17°3248, combining the new elementaldeterminations for Os-Pt and recently published Nd and Ho measurements,show excellent agreement with the solar system r-process curve from theelements Ba to Pb. The lighter n-capture elements, including Ge, ingeneral fall below the same solar system r-process curve that matchesthe heavier elements.

Stellar Chemical Signatures and Hierarchical Galaxy Formation
To compare the chemistries of stars in the Milky Way dwarf spheroidal(dSph) satellite galaxies with stars in the Galaxy, we have compiled alarge sample of Galactic stellar abundances from the literature. Whenkinematic information is available, we have assigned the stars tostandard Galactic components through Bayesian classification based onGaussian velocity ellipsoids. As found in previous studies, the[α/Fe] ratios of most stars in the dSph galaxies are generallylower than similar metallicity Galactic stars in this extended sample.Our kinematically selected stars confirm this for the Galactic halo,thin-disk, and thick-disk components. There is marginal overlap in thelow [α/Fe] ratios between dSph stars and Galactic halo stars onextreme retrograde orbits (V<-420 km s-1), but this is notsupported by other element ratios. Other element ratios compared in thispaper include r- and s-process abundances, where we find a significantoffset in the [Y/Fe] ratios, which results in a large overabundance in[Ba/Y] in most dSph stars compared with Galactic stars. Thus, thechemical signatures of most of the dSph stars are distinct from thestars in each of the kinematic components of the Galaxy. This resultrules out continuous merging of low-mass galaxies similar to these dSphsatellites during the formation of the Galaxy. However, we do not ruleout very early merging of low-mass dwarf galaxies, since up to one-halfof the most metal-poor stars ([Fe/H]<=-1.8) have chemistries that arein fair agreement with Galactic halo stars. We also do not rule outmerging with higher mass galaxies, although we note that the LMC and theremnants of the Sgr dwarf galaxy are also chemically distinct from themajority of the Galactic halo stars. Formation of the Galaxy's thickdisk by heating of an old thin disk during a merger is also not ruledout; however, the Galaxy's thick disk itself cannot be comprised of theremnants from a low-mass (dSph) dwarf galaxy, nor of a high-mass dwarfgalaxy like the LMC or Sgr, because of differences in chemistry.The new and independent environments offered by the dSph galaxies alsoallow us to examine fundamental assumptions related to thenucleosynthesis of the elements. The metal-poor stars ([Fe/H]<=-1.8)in the dSph galaxies appear to have lower [Ca/Fe] and [Ti/Fe] than[Mg/Fe] ratios, unlike similar metallicity stars in the Galaxy.Predictions from the α-process (α-rich freeze-out) would beconsistent with this result if there have been a lack of hypernovae indSph galaxies. The α-process could also be responsible for thevery low Y abundances in the metal-poor stars in dSph's; since [La/Eu](and possibly [Ba/Eu]) are consistent with pure r-process results, thelow [Y/Eu] suggests a separate r-process site for this light(first-peak) r-process element. We also discuss SNe II rates and yieldsas other alternatives, however. In stars with higher metallicities([Fe/H]>=-1.8), contributions from the s-process are expected; [(Y,La, and Ba)/Eu] all rise as expected, and yet [Ba/Y] is still muchhigher in the dSph stars than similar metallicity Galactic stars. Thisresult is consistent with s-process contributions from lower metallicityAGB stars in dSph galaxies, and is in good agreement with the slowerchemical evolution expected in the low-mass dSph galaxies relative tothe Galaxy, such that the build-up of metals occurs over much longertimescales. Future investigations of nucleosynthetic constraints (aswell as galaxy formation and evolution) will require an examination ofmany stars within individual dwarf galaxies.Finally, the Na-Ni trend reported in 1997 by Nissen & Schuster isconfirmed in Galactic halo stars, but we discuss this in terms of thegeneral nucleosynthesis of neutron-rich elements. We do not confirm thatthe Na-Ni trend is related to the accretion of dSph galaxies in theGalactic halo.

Spectroscopic Studies of Extremely Metal-Poor Stars with the Subaru High Dispersion Spectrograph. I. Observational Data
We have obtained high-resolution (R~=50,000 or 90,000), high-quality(S/N>~100) spectra of 22 very metal-poor stars ([Fe/H]<~-2.5) withthe High Dispersion Spectrograph fabricated for the 8.2 m SubaruTelescope. The spectra cover the wavelength range from 3500 to 5100Å equivalent widths are measured for isolated lines of numerouselemental species, including the α-elements, the iron-peakelements, and the light and heavy neutron-capture elements. Errors inthe measurements and comparisons with previous studies are discussed.These data will be used to perform detailed abundance analyses in thefollowing papers of this series. Radial velocities are also reported andare compared with previous studies. At least one moderatelyr-process-enhanced metal-poor star, HD 186478, exhibits evidence of asmall-amplitude radial velocity variation, confirming the binary statusnoted previously. During the course of this initial program, we havediscovered a new moderately r-process-enhanced, very metal-poor star, CS30306-132 ([Fe/H]=-2.4 [Eu/Fe]=+0.85), which is discussed in detail inthe companion paper.Based on data collected at Subaru Telescope, which is operated by theNational Astronomical Observatory of Japan.

Spectroscopic Studies of Extremely Metal-Poor Stars with the Subaru High Dispersion Spectrograph. II. The r-Process Elements, Including Thorium
We have obtained high-resolution, high signal-to-noise near-UV-bluespectra of 22 very metal-poor stars ([Fe/H]<-2.5) with the SubaruHigh Dispersion Spectrograph and measured the abundances of elementsfrom C to Th. The metallicity range of the observed stars is-3.2<[Fe/H]<-2.4. As found by previous studies, the star-to-starscatter in the measured abundances of neutron-capture elements in thesestars is very large, much greater than could be assigned toobservational errors, in comparison with the relatively small scatter inthe α- and iron-peak elements. In spite of the large scatter inthe ratios of the neutron-capture elements relative to iron, theabundance patterns of heavy neutron-capture elements (56<=Z<~72)are quite similar within our sample stars. The Ba/Eu ratios in the 11very metal-poor stars in our sample in which both elements have beendetected are nearly equal to that of the solar system r-processcomponent. Moreover, the abundance patterns of the heavy neutron-captureelements (56<=Z<=70) in seven objects with clear enhancements ofthe neutron-capture elements are similar to that of the solar systemr-process component. These results prove that heavy neutron-captureelements in these objects are primarily synthesized by the r-process. Incontrast, the abundance ratios of the light neutron-capture elements(38<=Z<=46) relative to the heavier ones (56<=Z<=70) exhibita large dispersion. Our inspection of the correlation between Sr and Baabundances in very metal-poor stars reveals that the dispersion of theSr abundances clearly decreases with increasing Ba abundance. This trendis naturally explained by hypothesizing the existence of two processes,one that produces Sr without Ba and another that produces Sr and Ba insimilar proportions. This result should provide a strong constraint onthe origin of the light neutron-capture elements at low metallicity. Wehave identified a new highly r-process element enhanced, metal-poorstar, CS 22183-031, a giant with [Fe/H]=-2.93 and [Eu/Fe]=+1.2. We alsoidentified a new, moderately r-process-enhanced, metal-poor star, CS30306-132, a giant with [Fe/H]=-2.42 and [Eu/Fe]=+0.85. The abundanceratio of the radioactive element Th (Z=90) relative to the stablerare-earth elements (e.g., Eu) in very metal-poor stars has been used asa cosmochronometer by a number of previous authors. Thorium is detectedin seven stars in our sample, including four objects for which thedetection of Th has already been reported. New detections of thoriumhave been made for the stars HD 6268, HD 110184, and CS 30306-132. TheTh/Eu abundance ratios [log(Th/Eu)], are distributed over the range-0.10 to -0.59, with typical errors of 0.10 to 0.15 dex. In particular,the ratios in two stars, CS 31082-001 and CS 30306-132, aresignificantly higher than the ratio in the well-studied object CS22892-052 and those of other moderately r-process-enhanced metal-poorstars previously reported. Since these very metal-poor stars arebelieved to be formed in the early Galaxy, this result suggests that theabundance ratios between Th and stable rare-earth elements such as Eu,both of which are presumably produced by r-process nucleosynthesis, mayexhibit real star-to-star scatter, with implications for (1) theastrophysical sites of the r-process, and (2) the use of Th/Eu as acosmochronometer.Based on data collected at the Subaru Telescope, which is operated bythe National Astronomical Observatory of Japan.

Neutron-Capture Elements in Halo, Thick-Disk, and Thin-Disk Stars: Neodymium
We have derived the LTE neodymium abundances in 60 cool stars withmetallicities [Fe/H] from 0.25 to -1.71 by applying a synthetic-spectrumanalysis to spectroscopic observations of NdII lines with a resolutionof λ/Δλ⋍60 000 and signal-to-noise ratios of100 200. We have improved the atomic parameters of NdII and blendinglines by analyzing the corresponding line pro files in the solarspectrum. Neodymium is overabundant with respect to iron in halo stars,[Nd/Fe]=0.33±0.09, with the [Nd/Fe] ratio decreasingsystematically with metallicity when [Fe/H]>-1. This reflects anonset of efficient iron production in type I supernovae during theformation of the thick disk. The [Nd/Ba] and [Nd/Eu] abundance ratiosbehave differently in halo, thick-disk, and thin-disk stars. Theobserved abundance ratios in halo stars, [Nd/Ba]=0.34±0.08 and[Nd/Eu]=-0.27±0.05, agree within the errors with the ratios ofthe elemental yields for the r-process. These results support theconclusion of other authors based on analyses of other elements that ther-process played the dominant role in the synthesis of heavy elementsduring the formation of the halo. The [Nd/Ba] and [Nd/Eu] ratios forthick-disk stars are almost independent of metallicity([Nd/Ba]=0.28(±0.03)-0.01(±0.04) [Fe/H] and[Nd/Eu]=-0.13(±0.03)+0.05(±0.04) [Fe/H]) but are smallerin absolute value than the corresponding ratios for halo stars,suggesting that the synthesis of s-process nuclei started during theformation of the thick disk. The s-process is estimated to havecontributed ⋍30% of the neodymium produced during this stage ofthe evolution of the Galaxy. The [Nd/Ba] ratio decreases abruptly by0.17 dex in the transition from the thick to the thin disk. Thesystematic decrease of [Nd/Ba] and increase of [Nd/Eu] with increasingmetallicity of thin-disk stars point toward a dominant role of thes-process in the synthesis of heavy elements during this epoch.

Empirically Constrained Color-Temperature Relations. II. uvby
A new grid of theoretical color indices for the Strömgren uvbyphotometric system has been derived from MARCS model atmospheres and SSGsynthetic spectra for cool dwarf and giant stars having-3.0<=[Fe/H]<=+0.5 and 3000<=Teff<=8000 K. Atwarmer temperatures (i.e., 8000-2.0. To overcome thisproblem, the theoretical indices at intermediate and high metallicitieshave been corrected using a set of color calibrations based on fieldstars having well-determined distances from Hipparcos, accurateTeff estimates from the infrared flux method, andspectroscopic [Fe/H] values. In contrast with Paper I, star clustersplayed only a minor role in this analysis in that they provided asupplementary constraint on the color corrections for cool dwarf starswith Teff<=5500 K. They were mainly used to test thecolor-Teff relations and, encouragingly, isochrones thatemploy the transformations derived in this study are able to reproducethe observed CMDs (involving u-v, v-b, and b-y colors) for a number ofopen and globular clusters (including M67, the Hyades, and 47 Tuc)rather well. Moreover, our interpretations of such data are verysimilar, if not identical, with those given in Paper I from aconsideration of BV(RI)C observations for the sameclusters-which provides a compelling argument in support of thecolor-Teff relations that are reported in both studies. Inthe present investigation, we have also analyzed the observedStrömgren photometry for the classic Population II subdwarfs,compared our ``final'' (b-y)-Teff relationship with thosederived empirically in a number of recent studies and examined in somedetail the dependence of the m1 index on [Fe/H].Based, in part, on observations made with the Nordic Optical Telescope,operated jointly on the island of La Palma by Denmark, Finland, Iceland,Norway, and Sweden, in the Spanish Observatorio del Roque de losMuchachos of the Instituto de Astrofisica de Canarias.Based, in part, on observations obtained with the Danish 1.54 mtelescope at the European Southern Observatory, La Silla, Chile.

Spectroscopic Binaries, Velocity Jitter, and Rotation in Field Metal-poor Red Giant and Red Horizontal-Branch Stars
We summarize 2007 radial velocity measurements of 91 metal-poor fieldred giants. Excluding binary systems with orbital solutions, ourcoverage averages 13.7 yr per star, with a maximum of 18.0 yr. We reportfour significant findings. (1) Sixteen stars are found to bespectroscopic binaries, and we present orbital solutions for 14 of them.The spectroscopic binary frequency of the metal-poor red giants, with[Fe/H]<=-1.4, for periods less than 6000 days, is 16%+/-4%, which isnot significantly different from that of comparable-metallicity fielddwarfs, 17%+/-2%. The two CH stars in our program, BD -1°2582 and HD135148, are both spectroscopic binaries. (2) Velocity jitter is presentamong about 40% of the giants with MV<=-1.4. The twobest-observed cases, HD 3008 and BD +22°2411, showpseudoperiodicities of 172 and 186 days, longer than any knownlong-period variable in metal-poor globular clusters. Photometricvariability seen in HD 3008 and three other stars showing velocityjitter hints that starspots are the cause. However, the phasing of thevelocity data with the photometry data from Hipparcos is not consistentwith a simple starspot model for HD 3008. We argue against orbitalmotion effects and radial pulsation, so rotational modulation remainsthe best explanation. The implied rotational velocities for HD 3008 andBD +22°2411, both with MV<=-1.4 and R~50Rsolar, exceed 12 km s-1. (3) Including HD 3008and BD +22°2411, we have found signs of significant excess linebroadening in eight of the 17 red giants with MV<=-1.4,which we interpret as rotation. In three cases, BD +30°2034, CD-37°14010, and HD 218732, the rotation is probably induced by tidallocking between axial rotation and the observed orbital motion with astellar companion. But this cannot explain the other five stars in oursample that display signs of significant rotation. This high frequencyof elevated rotational velocities does not appear to be caused bystellar mass transfer or mergers: there are too few main-sequencebinaries with short enough periods. We also note that the lack of anynoticeable increase in mean rotation at the magnitude level of the redgiant branch luminosity function ``bump'' argues against the rapidrotation's being caused by the transport of internal angular momentum tothe surface. Capture of a planetary-mass companion as a red giantexpands in radius could explain the high rotational velocities. (4) Wealso find significant rotation in at least six of the roughly 15 (40%)red horizontal-branch stars in our survey. It is likely that theenhanced rotation seen among a significant fraction of both blue and redhorizontal-branch stars arose when these stars were luminous red giants.Rapid rotation alone therefore appears insufficient cause to populatethe blue side of the horizontal branch. While the largest projectedrotational velocities seen among field blue and red horizontal-branchstars are consistent with their different sizes, neither are consistentwith the large values we find for the largest red giants. This suggeststhat some form of angular momentum loss (and possibly mass loss) hasbeen at work. Also puzzling is the apparent absence of rotation seen infield RR Lyrae variables. Angular momentum transfer and conservation inevolved metal-poor field stars thus pose many interesting questions forthe evolution of low-mass stars.

Probing the Neutron-Capture Nucleosynthesis History of Galactic Matter
The heavy elements formed by neutron-capture processes have aninteresting history from which we can extract useful clues to andconstraints upon both the characteristics of the processes themselvesand the star formation and nucleosynthesis history of Galactic matter.Of particular interest in this regard are the heavy-element compositionsof extremely metal deficient stars. At metallicities [Fe/H]<=-2.5,the elements in the mass region past barium (A>~130-140) have beenfound (in non-carbon-rich stars) to be pure r-process products. Theidentification of an environment provided by massive stars andassociated Type II supernovae as an r-process site seems compelling.Increasing levels of heavy s-process (e.g., barium) enrichment withincreasing metallicity, evident in the abundances of more metal richhalo stars and disk stars, reflect the delayed contributions from thelow- and intermediate-mass (M~1-3 Msolar) stars that providethe site for the main s-process nucleosynthesis component during theasymptotic giant branch phase of their evolution. New abundance data inthe mass region 60<~A<~130 are providing insight into the identityof possible alternative r-process sites. We review recent observationalstudies of heavy-element abundances in both low-metallicity halo starsand disk stars, discuss the observed trends in light of nucleosynthesistheory, and explore some implications of these results for Galacticchemical evolution, nucleosynthesis, and nucleocosmochronology.

The r-Process in the Early Galaxy
We report Sr, Pd, and Ag abundances for a sample of metal-poor fieldgiants and analyze a larger sample of Y, Zr, and Ba abundances. The[Y/Zr] and [Pd/Ag] abundance ratios are similar to those measured forthe r-process-rich stars CS 22892-052 and CS 31082-001. The [Pd/Ag]ratio is larger than predicted from the solar system r-processabundances. The constant [Y/Zr] and [Sr/Y] values in the field starsplace strong limits on the contributions of the weak s-process and themain s-process to the light neutron-capture elements. Stars in theglobular cluster M15 possess lower [Y/Zr] values than the field stars.There is a large dispersion in [Y/Ba]. Because the r-process isresponsible for the production of the heavy elements in the earlyGalaxy, these dispersions require varying light-to-heavy ratios inr-process yields.

Abundances of 30 Elements in 23 Metal-Poor Stars
We report the abundances of 30 elements in 23 metal-poor([Fe/H]<-1.7) giants. These are based on 7774 equivalent widths andspectral synthesis of 229 additional lines. Hyperfine splitting is takeninto account when appropriate. Our choice of model atmospheres has themost influence on the accuracy of our abundances. We consider the effectof different model atmospheres on our results. In addition to the randomerrors in Teff, logg, and microturbulent velocity, there areseveral sources of systematic error. These include using Teffdetermined from Fe I lines rather than colors, ignoring non-LTE effectson the Fe I/Fe II ionization balance, using models with solar[α/Fe] ratios, and using Kurucz models with overshooting. Ofthese, only the use of models with solar [α/Fe] ratios had anegligible effect. However, while the absolute abundances can change bygreater than 0.10 dex, the relative abundances, especially betweenclosely allied atoms such as the rare earth group, often show only small(less than 0.03 dex) changes. We found that some strong lines of Fe I,Mn I, and Cr I consistently gave lower abundances by ~0.2 dex, a numberlarger than the quoted errors in the gf-values. After considering amodel with depth-dependent microturbulent velocity and a model withhotter temperatures in the upper layers, we conclude that the latter dida better job of resolving the problem and agreeing with observationalevidence for the structure of stars. The error analysis includes theeffects of correlation of Teff, logg, and ξ errors, whichis crucial for certain element ratios, such as [Mg/Fe]. The abundancespresented here are being analyzed and discussed in a separate series ofpapers.

Abundances and Kinematics of Field Stars. II. Kinematics and Abundance Relationships
As an investigation of the origin of ``α-poor'' halo stars, weanalyze kinematic and abundance data for 73 intermediate-metallicitystars (-1>[Fe/H]>=-2) selected from Paper I of this series. We findevidence for a connection between the kinematics and the enhancement ofcertain element-to-iron ([X/Fe]) ratios in these stars. Statisticallysignificant correlations were found between [X/Fe] and galacticrest-frame velocities (vRF) for Na, Mg, Al, Si, Ca, and Ni,with marginally significant correlations existing for Ti and Y as well.We also find that the [X/Fe] ratios for these elements all correlatewith a similar level of significance with [Na/Fe]. Finally, we comparethe abundances of these halo stars against those of stars in nearbydwarf spheroidal (dSph) galaxies. We find significant differencesbetween the abundance ratios in the dSph stars and halo stars of similarmetallicity. From this result, it is unlikely that the halo stars in thesolar neighborhood, including even the ``α-poor'' stars, were oncemembers of disrupted dSph galaxies similar to those studied to date.

12C/13C in Metal-poor Field Halo Giants
We have estimated 12C/13C in 15 metal-poor(-2.4<=[Fe/H]<=-1.0) field halo giant stars from spectra of the13CO v=3-1 and v=2-0 band heads and surrounding12CO and 13CO R-branch lines. Our isotope ratiosare consistent with previous measurements for stars in our sample with12C/13C determined either from the infraredfirst-overtone bands of CO or from optical G-band spectra of CH and redsystem bands of CN. We have also compiled carbon isotope ratios from theliterature for a much larger sample of field and cluster red giantbranch (RGB) stars spanning a wide range of metallicities(-2.4<=[Fe/H]<=solar). Combining these data, we confirm thedecline of the isotope ratio as stars evolve up the RGB and we haveidentified a trend toward higher levels of mixing in more metal-poorstars. Standard RGB first dredge-up models do not predict the carbonisotope ratios that we observe in the more evolved (higher luminosity)metal-poor stars, but more recent models that account for other mixingmechanisms can explain these data; even for very metal-poor stars suchas those that we have observed in the Galactic halo.

A Model for Abundances in Metal-poor Stars
A model is presented that seeks to explain quantitatively the stellarabundances of r-process elements and other elements associated with ther-process sites. It is argued that the abundances of all these elementsin stars with -3<~[Fe/H]<-1 can be explained by the contributionsof three sources. The sources are the first generations of very massive(>~100 Msolar) stars that are formed from big bang debrisand are distinct from Type II supernovae (SNe II) and two types of SNeII, the H and L events, which can occur only at [Fe/H]>~-3. The Hevents are of high frequency and produce dominantly heavy (A>130)r-elements but no Fe (presumably leaving behind black holes). The Levents are of low frequency and produce Fe and dominantly light(A<~130) r-elements (essentially none above Ba). By using theobserved abundances in two ultra-metal-poor stars and the solarr-abundances, the initial or prompt inventory of elements produced bythe first generations of very massive stars and the yields of H and Levents can be determined. The abundances of a large number of elementsin a star can then be calculated from the model by using only theobserved Eu and Fe abundances. To match the model results and theobservational data for stars with -3<[Fe/H]<-1 requires that thesolar r-abundances for Sr, Y, Zr, and Ba must be significantly increasedfrom the standard values. No such changes appear to be required for allother elements. If the changes in the solar r-abundances for Sr, Y, Zr,and Ba are not permitted, the model fails at -3<[Fe/H]<-1 butstill works at [Fe/H]~-3 for these four elements. By using the correctedsolar r-abundances for these elements, good agreement is obtainedbetween the model results and data over the range -3<[Fe/H]<-1. Noevidence of s-process contributions is found in this region, but all theobservational data in this region now show regular increases of Ba/Euabove the standard solar r-process value. Whether the solar r-componentsof Sr, Y, Zr, and Ba used here to obtain a fit to the stellar data canbe reconciled with those obtained from solar abundances by subtractingthe s-components calculated from models is not clear.

Th Ages for Metal-poor Stars
With a sample of 22 metal-poor stars, we demonstrate that theheavy-element abundance pattern (Z>=56) is the same as the r-processcontributions to the solar nebula. This bolsters the results of previousstudies that there is a universal r-process production pattern. We usethe abundance of thorium in five metal-poor stars, along with anestimate of the initial Th abundance based on the abundances of stabler-process elements, to measure their ages. We have four field red giantswith errors of 4.2 Gyr in their ages and one M92 giant with an error of5.6 Gyr, based on considering the sources of observational error only.We obtain an average age of 11.4 Gyr, which depends critically on theassumption of an initial Th/Eu production ratio of 0.496. If theuniverse is 15 Gyr old, then the (Th/Eu)0 should be 0.590, inagreement with some theoretical models of the r-process.

Passbands and Theoretical Colors for the Washington System
The passbands of the Washington system (C, M, T1,T2) have been checked through synthetic photometry of theVilnius spectra and comparison of observed and synthetic color-colorrelations. Using the derived passbands, theoretical colors were computedusing the grid of ATLAS no-overshoot models of Castelli. These can beused for calibration of the Washington system.

Neutron-Capture Elements in the Early Galaxy: Insights from a Large Sample of Metal-poor Giants
New abundances for neutron-capture (n-capture) elements in a largesample of metal-poor giants from the Bond survey are presented. Thespectra were acquired with the KPNO 4 m echelle and coudé feedspectrographs, and have been analyzed using LTE fine-analysis techniqueswith both line analysis and spectral synthesis. Abundances of eightn-capture elements (Sr, Y, Zr, Ba, La, Nd, Eu, and Dy) in 43 stars havebeen derived from blue (λλ4070-4710, R~20,000, S/Nratio~100-200) echelle spectra and red (λλ6100-6180,R~22,000, S/N ratio~100-200) coudé spectra, and the abundance ofBa only has been derived from the red spectra for an additional 27stars. Overall, the abundances show clear evidence for a largestar-to-star dispersion in the heavy element-to-iron ratios. Thiscondition must have arisen from individual nucleosynthetic events inrapidly evolving halo progenitors that injected newly manufacturedn-capture elements into an inhomogeneous early Galactic halointerstellar medium. The new data also confirm that at metallicities[Fe/H]<~-2.4, the abundance pattern of the heavy (Z>=56) n-captureelements in most giants is well-matched to a scaled solar systemr-process nucleosynthesis pattern. The onset of the main r-process canbe seen at [Fe/H]~-2.9 this onset is consistent with the suggestion thatlow mass Type II supernovae are responsible for the r-process.Contributions from the s-process can first be seen in some stars withmetallicities as low as [Fe/H]~-2.75 and are present in most stars withmetallicities [Fe/H]>-2.3. The appearance of s-process contributionsas metallicity increases presumably reflects the longer stellarevolutionary timescale of the (low-mass) s-process nucleosynthesissites. The lighter n-capture elements (Sr-Y-Zr) are enhanced relative tothe heavier r-process element abundances. Their production cannot beattributed solely to any combination of the solar system r- and mains-processes, but requires a mixture of material from the r-process andfrom an additional n-capture process that can operate at early Galactictime. This additional process could be the weak s-process in massive(~25 Msolar) stars, or perhaps a second r-process site, i.e.,different from the site that produces the heavier (Z>=56) n-captureelements.

Abundances and Kinematics of Field Halo and Disk Stars. I. Observational Data and Abundance Analysis
We describe observations and abundance analysis of a high-resolution,high signal-to-noise ratio survey of 168 stars, most of which aremetal-poor dwarfs. We follow a self-consistent LTE analysis technique todetermine the stellar parameters and abundances, and we estimate theeffects of random and systematic uncertainties on the resultingabundances. Element-to-iron ratios are derived for key α-, odd-Z,Fe-peak, and r- and s-process elements. Effects of non-LTE on theanalysis of Fe I lines are shown to be very small on average.Spectroscopically determined surface gravities are derived that arequite close to those obtained from Hipparcos parallaxes.

Kinematics of Metal-poor Stars in the Galaxy. II. Proper Motions for a Large Nonkinematically Selected Sample
We present a revised catalog of 2106 Galactic stars, selected withoutkinematic bias and with available radial velocities, distance estimates,and metal abundances in the range -4.0<=[Fe/H]<=0.0. This updateof the 1995 Beers & Sommer-Larsen catalog includes newly derivedhomogeneous photometric distance estimates, revised radial velocitiesfor a number of stars with recently obtained high-resolution spectra,and refined metallicities for stars originally identified in the HKobjective-prism survey (which account for nearly half of the catalog)based on a recent recalibration. A subset of 1258 stars in this cataloghave available proper motions based on measurements obtained with theHipparcos astrometry satellite or taken from the updated AstrographicCatalogue (second epoch positions from either the Hubble Space TelescopeGuide Star Catalog or the Tycho Catalogue), the Yale/San Juan SouthernProper Motion Catalog 2.0, and the Lick Northern Proper Motion Catalog.Our present catalog includes 388 RR Lyrae variables (182 of which arenewly added), 38 variables of other types, and 1680 nonvariables, withdistances in the range 0.1 to 40 kpc.

Spectrophotometry: Revised Standards and Techniques
The telluric features redward of 6700 Å have been removed from theaccurate spectrophotometric standards of Hamuy et al. to permit morereliable relative and absolute spectrophotometry to be obtained from CCDspectra. Smooth fluxes from 3300 to 10500 Å are best determined bydividing the raw spectra of all objects taken in a night by the rawspectrum of a ``smooth'' spectrum star before deriving the instrumentalresponse function using the revised standard star fluxes. In this waythe telluric features and any large instrumental variation withwavelength are removed from the raw data, leaving smooth spectra thatneed only small corrections to place them on an absolute flux scale.These small corrections with wavelength are well described by alow-order polynomial and result in very smooth flux-calibrated spectra.

The effective temperature scale of giant stars (F0-K5). I. The effective temperature determination by means of the IRFM
We have applied the InfraRed Flux Method (IRFM) to a sample ofapproximately 500 giant stars in order to derive their effectivetemperatures with an internal mean accuracy of about 1.5% and a maximumuncertainty in the zero point of the order of 0.9%. For the applicationof the IRFM, we have used a homogeneous grid of theoretical modelatmosphere flux distributions developed by \cite[Kurucz (1993)]{K93}.The atmospheric parameters of the stars roughly cover the ranges: 3500 K<= T_eff <= 8000 K; -3.0 <= [Fe/H] <= +0.5; 0.5 <= log(g) <= 3.5. The monochromatic infrared fluxes at the continuum arebased on recent photometry with errors that satisfy the accuracyrequirements of the work. We have derived the bolometric correction ofgiant stars by using a new calibration which takes the effect ofmetallicity into account. Direct spectroscopic determinations ofmetallicity have been adopted where available, although estimates basedon photometric calibrations have been considered for some stars lackingspectroscopic ones. The adopted infrared absolute flux calibration,based on direct optical measurements of stellar angular diameters, putsthe effective temperatures determined in this work in the same scale asthose obtained by direct methods. We have derived up to fourtemperatures, TJ, TH, TK and T_{L'},for each star using the monochromatic fluxes at different infraredwavelengths in the photometric bands J, H, K and L'. They show goodconsistency over 4000 K, and there is no appreciable trend withwavelength, metallicity and/or temperature. We provide a detaileddescription of the steps followed for the application of the IRFM, aswell as the sources of error and their effect on final temperatures. Wealso provide a comparison of the results with previous work.

Estimation of Stellar Metal Abundance. II. A Recalibration of the Ca II K Technique, and the Autocorrelation Function Method
We have recalibrated a method for the estimation of stellar metalabundance, parameterized as [Fe/H], based on medium-resolution (1-2Å) optical spectra (the majority of which cover the wavelengthrange 3700-4500 Å). The equivalent width of the Ca II K line (3933Å) as a function of [Fe/H] and broadband B-V color, as predictedfrom spectrum synthesis and model atmosphere calculations, is comparedwith observations of 551 stars with high-resolution abundances availablefrom the literature (a sevenfold increase in the number of calibrationstars that were previously available). A second method, based on theFourier autocorrelation function technique first described by Ratnatunga& Freeman, is used to provide an independent estimate of [Fe/H], ascalibrated by comparison with 405 standard-star abundances.Metallicities based on a combination of the two techniques for dwarfsand giants in the color range 0.30<=(B-V)_0<=1.2 exhibit anexternal 1 sigma scatter of approximately 0.10-0.20 dex over theabundance range -4.0<=[Fe/H]<=0.5. Particular attention has beengiven to the determination of abundance estimates at the metal-rich endof the calibration, where our previous attempt suffered from aconsiderable zero-point offset. Radial velocities, accurate toapproximately 10 km s^-1, are reported for all 551 calibration stars.

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Observation and Astrometry data

Constellation:Waage
Right ascension:14h27m00.36s
Declination:-22°14'39.0"
Apparent magnitude:9.136
Proper motion RA:-14.9
Proper motion Dec:-52.1
B-T magnitude:10.065
V-T magnitude:9.213

Catalogs and designations:
Proper Names   (Edit)
HD 1989HD 126587
TYCHO-2 2000TYC 6164-1738-1
USNO-A2.0USNO-A2 0675-13324461
HIPHIP 70647

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